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This is not easy, this effort, day after day, week after week, to keep them up, but it is essential Each week there is a different challenge, but there is also that unavoidable degree of sameness to these meetings

Equations (1344) through (1346) then yield:

WeIec, -228 572 J mol-' =

Q = -13 246 J mol-'

And to some extent, the rougher parts of the job didn t come naturally to him Remember that he had once considered becoming a priest and, later, a teacher The rough-and-tumble of pro football, the emotion, the yelling, releasing players who have played their hearts out for you, just the hardness of the coaching profession, sometimes weighed heavily on him

If, as is more commonly the case, air is the source of oxygen, the cell receives O2 at its partial pressure in air Because the enthalpy of ideal gases is independent of pressure, the enthalpy change of reaction for the cell is unchanged However, the Gibbs-energy change of reaction is affected By Eq (1 126),

.

Therefore, on the basis of 1 mol of H 2 0 formed,

A G = AG;2g,

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It s no damn fun being hard I ve been doing this for years and years and years It s never been great fun You have to drive yourself constantly I don t enjoy it It takes a hell of a lot out of me And, Christ, you get kind of embarrassed with yourself sometimes You berate somebody, and you feel disgusted with yourself for doing it, for being in a job where you have to Fortunately, I don t remember

+ ( 0 5 ) ( ~ $ ~Gg2) -

1 Alkali metal (Group IA) hydroxides (LiOH, NaOH, KOH, RbOH, CsOH) 2 Ca(OH)2, Sr(OH)2, and Ba(OH)2 The strong bases listed above are all compounds that dissociate completely, yielding the hydroxide ion (which is really the base, not the compound) Unless told otherwise, assume that acids and bases not on the lists above are weak and will establish an equilibrium system when placed into water Some salts have acid base properties For example, ammonium chloride, NH4Cl, when dissolved in water will dissociate and the ammonium ion will act as a weak acid, donating a proton We will examine these acid base properties in more detail in the next section Certain oxides can have acidic or basic properties These properties often become evident when the oxides are dissolved in water In most case, reactions of this type are not redox reactions Many oxides of metals that have a +1 or +2 charge are called basic oxides (basic anhydrides), because they will react with acids Fe 2O3 ( s) + 6 HCl(aq ) 2 FeCl 3 (aq ) + 3 H2O( l ) Fe 2O3 ( s) + 6 H + (aq ) 2 Fe 3+ (aq ) + 3 H 2O(l ) Many times they react with water to form a basic solution: Na 2O( s) + H2O( l ) 2 NaOH(aq ) Na 2O(s) + H 2O(l ) 2 Na + (aq ) + 2 OH (aq ) Many nonmetal oxides are called acidic oxides (acidic anhydrides), because they react with water to form an acidic solution: CO2 ( g ) + H 2O(l ) H 2CO3 (aq ) H2CO3(aq) is named carbonic acid and is the reason that most carbonated beverages are slightly acidic It is also the reason that soft drinks have fizz, because carbonic acid will decompose to form carbon dioxide and water.

= A G k g 8- 05RT In yo,

But this was his job the job of a motivational and inspirational leader So he kept the pressure on his team, and he kept the pressure on himself

= -228 572 - (05)(8314)(29815)(ln021) = -226 638

Equations (1344) through (1346) now yield:

5 4 3 2 1

WeleCt -226 638 J mol-' = Q = -15 180 J mol-'

MOTIVATING THE TEAM: THE POWER OF FIRE AND PRAISE Coach Lombardi had a challenging task: to find a way to motivate and inspire several dozen prima donnas, many of whom had spent much of their childhood and adolescence as local heroes, with their physical accomplishments celebrated and their shortcomings mostly ignored

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