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The use of air rather than pure oxygen does not significantly reduce the emf and work output of a reversible cell The enthalpy and Gibbs-energy changes of reaction are given as functions of temperature by Eqs (418) and (1318) For a cell temperature of 33315 K (60 C), the integrals in these equations are evaluated as:

Equations (418) and (1318) then yield:

I am going to find 36 men who have the pride to make any sacrifice to win There are such men If they re not here, I ll get them If you are not one, if you don t want to play, you might as well leave right now

Extremely well-qualified for college credit Well-qualified Qualified Possibly qualified Not qualified

AG>333 -226 997 J mol-' =

Equations (1344) through (1346) now yield:

Q = - 17 332 J mol-'

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That s what my father told the Green Bay Packers on July 23, 1959, the day he first met with them officially as head coach In making this speech, Vince Lombardi was taking a calculated risk It was extremely difficult to get a handle on this group of men They were enormously frustrated following their miserable 1 10 1 record the previous year Even so, it was no sure bet that they would buy into this new guy, either Who was he, after all Only an assistant coach from New York My father half expected a number of these players some of the veterans, at least to take him up on his offer to leave right now As it turned out, no one left The gamble paid off: Lombardi had reached into them, found their pride as professionals, and put that pride on the table If you don t have pride, he said, leave now No one left

Thus cell operation at 33315 K (60 C) rather than at 29815 K (25 C)reduces the voltage and work output of a reversible cell by only a small amount These calculations for a reversible cell show that the electrical work output is more than 90% of the heat that would be released ( A H ) by actual combustion of the fuel Were this heat supplied to a Carnot engine operating at practical temperature levels, a much smaller

If you are enrolled in AP Chemistry in your high school, your teacher is going to provide all of these details You do not have to enroll in the AP course to register for and complete the AP exam When in doubt, the best source of information is the College Board s web site: wwwcollegeboardcom Students who demonstrate financial need may receive a refund to help offset the cost of testing There are also several optional fees that are necessary if you want your scores rushed to you, or if you wish, to receive multiple grade reports

fraction would be converted into work The reversible operation of a fuel cell implies that a potentiometer exactly balances its emf, with the result that its current output is negligible In actual operation under reasonable load, internal irreversibilities inevitably reduce the emf of the cell and decrease its production of electrical work, while increasing the amount of heat transfer to the surroundings The operating emf of hydrogenloxygen fuel cells is 06-07 volts, and its work output is closer to 50% of the heating value of the fuel Nevertheless, the irreversibilities of a fuel cell are far less than those inherent in combustion of the fuel It has the additional advantages of simplicity, of clean and quiet operation, and of directly producing electrical energy Fuels other than hydrogen may well be appropriate for fuel-cell use, but require development of effective catalysts Methanol, for example, reacts at the anode of a proton-exchange membrane fuel cell according to the equation:

131 Develop expressions for the mole fractions of reacting species as functions of the reaction coordinate for: (a) A system initially containing 2 rnol NH3 and 5 rnol O2 and undergoing the reaction:

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4NH3(g)

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